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Spectroscopic study of side-chain melting and crystallization of regioregular poly(3- dodecylthiophene)
Journal article

Spectroscopic study of side-chain melting and crystallization of regioregular poly(3- dodecylthiophene)

Ying Jin, Yan Guo and Zhaohui Su
Polymer chemistry, Vol.3(4), pp.861-864
02/03/2012
Handle:
https://hdl.handle.net/20.500.12741/rep:9877

Abstract

Polymer Chemistry

Regioregular poly(3-dodecylthiophene) was investigated by temperature-dependent FTIR. Clear turning points were observed at ∼80 °C in variations of vibrational bands associated with the alkyl side chains, indicating that the thermal transitions at this temperature are side-chain melting/crystallization. In contrast, no such turning points were found for poly(3-hexylthiophene).

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