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Rotational spectrum of the dimethyl ether-acetylene complex: Evidence for an effective C geometry
Journal article   Peer reviewed

Rotational spectrum of the dimethyl ether-acetylene complex: Evidence for an effective C geometry

Josh J Newby, Michal M Serafin, Rebecca A Peebles and Sean A Peebles
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, Vol.109(24), p.5316
06/23/2005

Abstract

Carbon compounds Fourier transform infrared spectroscopy Methyl ether Spectra
The rotational spectra for five isotopomers of the 1:1 weakly bound complex formed between dimethyl ether (DME) and acetylene (HCCH) is measured by Fourier transform microwave spectroscopy. The structural parameters and energetics of the DME-HCCH complex is discussed and compared to similar complexes such as H2O-HCHH.

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