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Additional mass transport considerations in the formation of hydroxyalkylsulfonates
Journal article

Additional mass transport considerations in the formation of hydroxyalkylsulfonates

Roy W Dixon
Atmospheric environment. Part A, General topics, Vol.26(5), pp.899-905
1992
Handle:
https://hdl.handle.net/20.500.12741/rep:8025

Abstract

mass-transport Hydroxyalkylsulfonate cloud chemistry formaldehyde hydroxymethanesulfonate
The formation rates of hydroxyalkylsulfonates in cloud droplets was examined with consideration of aldehyde mass transport to droplets and hydration rates of aldehydes in cloud droplets. Detailed calculations were performed for hydroxymethanesulfonate formation in cloud droplets. It was found that mass transport of formaldehyde into droplets can occur rapidly enough so that methylene glycol dehydration is not the rate limiting step as it is, under certain conditions, in a closed system.

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